CL206

CHEMICAL ENGINEERING THERMODYNAMICS

 

FACULTY MEMBER :Prof.S. SUNDARAM

OBJECTIVE : To educate the students in the area of thermodynamics as applied to various Chemical Engineering Processes.

1. FUNDAMENTALS OF THERMODYNAMICS:

Laws of thermodynamics as applied to open and closed system - reversible and irreversible processes - state and point function - Absolute entropy - Thermodynamic property changes for ideal gas.

2. PVT RELATIONS:

PVT relationships for gases and liquids - equations of state - Z charts - gas mixtures. Compression - expansion. Refrigeration: Principles and application.

3. THERMODYNAMIC RELATIONS:

Thermodynamic relations - Maxwell's relations - Jacobian algebra - estimation of thermodynamic properties.

4. PHASE EQUILIBRIA:

Phase equilibria - pure component and mixtures - Latent heat correlation - van Laar, Margules equations - Gibbs' - Duhem equation - consistency tests - partially miscible and immiscible systems - Azeotropes - retrograde condensation - thermodynamic diagrams.

5. CHEMICAL EQUILIBRIA:

Chemical equilibria - heat effects, industrial reactions - Free energy calculations - Homogeneous and heterogeneous reactions - Industrial reactions like NH3 synthesis, SO3 production etc.

TEXTBOOKS:

1. J. M. Smith and Van Ness, "Introduction to Engineering Thermodynamics", McGraw Hill, New York, 1994.

2. S. Sundaram, " Chemical Engineering Thermodynamics", Ahuja Publishers, New Delhi, 1998.

 

REFERENCE:

1. B.F. Dodge, "Chemical Engineering Thermodynamics", McGraw Hill, New York, 1971.